Theory & Terms
color
basics
Before you embark on selecting colors for your products, a knowledge base on the fundamentals of color theory, color chemistry, and color properties is helpful and important.
color
theory
When evaluating a color for your cosmetics, there are three key elements that need to be considered.
Light Source
What is the source of light that the color will be viewed in: natural (sunlight) or artificial (fluorescent or incandescent).
Element Application
What is the element or product that you will be applying the color to (for example: lipstick, blush, etc).
Target Audience
What is the receptor or intended audience? (for example: the human eye for cosmetics).
Color additives fall into one of two broad categories: Dyes and Pigments
Generally, in cosmetics, the term solubility refers to water solubility. The majority of colors used in decorative cosmetics are pigments. All the colors we sell at Just Pigments will fall into the pigment category.
More About Our
products
The range of inorganic pigments used in cosmetics is made up of several different chemical types. In general, inorganic pigments are duller in color than their brighter organic counterparts. They are far superior, though, in their stability to heat and light. They can react in extreme conditions of pH. For example, ultramarines can react with acids and produce hydrogen sulphide as a by-product. They are inorganic pigments and may be used in cosmetics subject to their purity levels of heavy metals.
These inorganic pigments are used in all types of cosmetics and have three basic shades: black, yellow, and red. By blending these three oxides in the right proportions, you can produce an array of browns, tans, and umbers for liquid foundations, face powders, and blushers. By careful blending, an array of natural-looking flesh tones may be produced.
Chromium dioxides is used for most cosmetic and industrial applications but are not permitted for use in lip products in the USA. The colors range from dull olive green to blue-green or bright green.
Ultramarines vary in shade from bright blue to violet, pink and even green. Ultramarine blue is not permitted in lip products in the USA.
This brightly colored inorganic pigment is purple-colored. It is approved for all cosmetic use but may turn grey in high pH applications.
This very deep, intense dark blue pigment is widely used in all cosmetic applications. It is not permitted in lip products in the USA.
White pigments are widely used in all cosmetics. They have extremely good covering power and are almost totally inert, in addition to being extremely stable to heat and light. Titanium Dioxide and Zinc Oxide are the most commonly used in cosmetics.
Chemically, mica is a potassium aluminium silicate dihydrate. It is mined as the ore muscovite and occurs in multi-layered bright translucent sheets. Cosmetic Mica is refined and ground. Mica imparts a natural translucence to face powders and powder blushers when used at levels up to 40%.
Plate-like crystals that have a highly refractive index. The pearlescent effect is obtained as a result of individual plates lining up and acting like tiny mirrors. There are various types of materials used in cosmetics to produce this effect.
Organic cosmetic pearls produce a bright silver effect and are only available from fish scales. Although they are still available but in short supply, organic pearls are very expensive and have almost exclusively been replaced by synthetic organic pearls.
Bismuth Oxychloride produces a silver-grey pearlescent effect. The effect is based on the crystal size. A smaller crystal size gives an opaque smooth lustre and a larger crystal size gives a more brilliant sparkling effect.
Titanium is used to coat platelets of mica. Titanium can exist in two crystal forms, either anatase or rutile. The rutile crystals give a particularly brilliant pearl effect, caused by their higher refractive index.
In addition to ultra-thin layers of titanium dioxide being deposited onto mica, colored pigments can also be laminated with this interference film. This produces a two-color effect caused by the light rays being reflected and refracted or transmitted at the different pigment layers.
Colored pearls consist of layers of titanium-coated mica, with an additional color and lustre effect that is purer than can be achieved by simply mixing pigment with silvery (rutile) pearls.
There are three types of organic pigments: lakes, toners, and true pigments.
· Lakes are pigments made by absorbing the dye onto a substrate such as alumina hydrate. There is no chemical bond between the dye and the substrate. The dye takes on the insoluble nature of the substrate. Based on the absorptive powers of the substrate, the amount of dye in the lake may range from 12-60%.
· Toners are more resistant to light and heat, but extreme pH can change the shade.
· True pigments are the most stable, but they are relatively uncommon.
Terms &
glossary
Binders: Pressed face powder and eye shadow are extremely popular because they can be easily carried and applied. In order for a free-flowing powder to be pressed into cosmetic containers, a liquid binder has to be uniformly dispersed through it. Binders usually consist of powders such as zinc stearate or magnesium stearate or oils such as jojoba oil or fractionated coconut oil. Glycerin or alcohol may wet a product, but it will not bind them together. Glycerin may attract moisture from the air and contaminate your powder.
Certified Lot Number: This is the identifying number assigned to each batch of colorant by the FDA when a manufacturing company’s submitted batch is certified. It is unique to that color and that batch.
Hue: The hue or shade of color is described by using the color Index (CI) terminology. It is a method that was developed to standardize the verbal description of colors.
Safety: All the certified dyes listed for use in the US have been tested at least three times. “Safe” is determined by law as “convincing evidence that establishes with reasonable certainty that no harm will result from the intended use of the color additive.
The Color Index (CI): This is the best-known reference book on color, edited jointly by the Society of Dyers and colorists and the American Association of Textile Chemists and colorists. No matter what language one speaks, if the CI number is known, the chemical, structural, and physical properties of the colorant are available.
The Code of Federal Regulations (CFR): The CFR is the codification of the rules published in the Federal Register by the Executive branch and the agencies of the U.S. Federal Government. It is updated annually.
FD & C colors: for use in food, drug and cosmetics.
D&C colors: for use in drugs and cosmetics.
Ext. D&C Colors: Colors for use in externally applied drugs and cosmetics which do not come into contact with mucous membranes.
Colors
For the most part, the inorganic pigments, pearlescent pigments, and Lakes are what we will use and sell at Just Pigments. They are generally the safest and most approved colors for use in eye shadows, powders, blushes, mascara, and eyeliner. It is important that the pigments used are specially produced for cosmetics and purified with no heavy metals. They are also used for many other industrial purposes, such as paint, resin, polymer clay, and so on.
Dyes: colorants which are soluble in vehicles such as water, alcohol, glycerin, or oils.
Natural Dyes: Apart from purity considerations, natural dyes are widely used in foodstuffs. There is no restriction on the use of natural dyes in cosmetics. In general, natural dyes are not resistant to heat, light, and pH stability. This makes them much inferior to their synthetic counterparts. They should be thoroughly tested in finished products. In some instances, natural dyes exhibit strong odours. Just Pigments does not sell any colors for ingestion or natural pigments made from fruit, vegetables, or animals.
Pigments: Colorants which are insoluble in the vehicle in which they are used. They are generally referred to as “dispersible,” meaning they will mix with water or oil.
Acid Dyes: All water-soluble dyes are classified chemically as acid dyes. Acid dyes are usually the sodium salts of sulfonated or carboxylated dye molecules.
Solvent Dyes: The oil-soluble or non-polar dyes are those which have no salt-forming groups on the dye molecule. They will dissolve in hydrocarbons, oils, waxes, and aromatic solvents.
Pure Dye: This is the amount of dye actually contained in the certified colorant, exclusive of inorganic salts, moisture, side reaction products, or unreacted intermediates.
The Effects of Particular Size
Different effects can be achieved by the right choice of pigment and particle size. Small particles (less than 15 microns) create silky and satin effects and will opacify the mass. Larger-sized particles (larger than 100 microns) create high-lustre effects, either sparkling or glittering, combined with high brilliance and transparency.
There are a few basic rules that we follow when formulating with pearl lustre pigments.
Color EFFECT vs. PARTICLE SIZE
Particle Size 15 µm or less = low lustre, good hiding power
Particle Size 2-25 µm = silky lustre and strong hiding powder
Particle Size 10-60 µm = pearl lustre with medium hiding power
Particle Size 10-125 µm = shimmering lustre and low hiding power
Particle Size 20-150 µm = sparkling lustre and transparent
Particle Size 45-500 µm = glittering lustre and very transparent
MICA pigments with a particle size of over 150 µm are not permitted on the FACE in the US.
This information about particle size will come in handy when it comes time to make up your own recipes. If you are making a transparent powder, the less opacity the formulation has, the better your pearlescent effect will be. In these transparent powders, the amount of pigment is fairly low compared to the ratio of MICA and fillers.
Pearlescent pigments should never be ground with a mortar and pestle. By grinding them, you break or remove the metal oxide from the mica plates, which will result in a loss of lustre and a change in color. Pearl pigments are easy to mix into other ingredients and can always be mixed in at the end.
Oxides and lake pigments do not have a lustrous effect and are difficult to blend. Conventional oxides are very difficult to get properly dispersed without high-speed mixing equipment.